Unraveling the Role of Solvation and Ion Valency on Redox-Mediated Electrosorption through In Situ Neutron...

Solvation and ion valency effects on selectivity of metal oxyanions at redox-polymer interfaces are explored through in situ spatial-temporally resolved neutron reflectometry combined with large scale ab initio molecular dynamics. The selectivity of ReO₄^- vs MoO₄^2- for two redox-metallopolymers, poly(vinyl ferrocene) (PVFc) and poly(3-ferrocenylpropyl methacrylamide) (PFPMAm) is evaluated. PVFc has a higher Re/Mo separation factor compared to PFPMAm at 0.6 V vs Ag/AgCl. In situ techniques show that both PVFc and PFPMAm swell in the presence of ReO₄^- (having higher solvation with PFPMAm), but do not swell in contact with MoO₄^2-. Ab initio molecular simulations suggest that MoO₄^2- maintains a well-defined double solvation shell compared to ReO₄^-. The more loosely solvated anion (ReO₄^-) is preferably adsorbed by the more hydrophobic redox polymer (PVFc), and electrostatic cross-linking driven by divalent anionic interactions could impair film swelling. Thus, the in-depth understanding of selectivity mechanisms can accelerate the design of ion-selective redox-mediated separation systems for transition metal recovery and recycling.