SnO₂QDs sensitized ZnFe₂O₄spheres with enhanced acetone sensing performance

Herein, SnO₂QDs (<10 nm) with small size instead of conventional nanoparticles was employed to modify ZnFe₂O₄to synthesize porous and heterogeneous SnO₂/ZnFe₂O₄(ZFSQ) composites for gas sensing. By an immersion process combined with calcination treatment, the resultant porous ZFSQ composites with different contents of SnO₂QDs were obtained, and their sensing properties were investigated. Compared with bare ZnFe₂O₄and SnO₂QDs, porous ZFSQ composites based-sensors showed much improved sensor response to acetone. For contrast, the sensor performance of ZFSQ composites was also compared with that of ZnFe₂O₄sphere modified by SnO₂nanoparticles with different size. The porous ZFSQ composite with 5 wt% SnO₂QDs (ZFSQ-5) showed a better acetone sensing response than that of other ZFSQ composites, and it exhibited a high response value of 110-100 ppm of acetone and a low detection limit of 0.3 ppm at 240 °C. In addition to the rich heterojunctions and porous structure, the size effect of SnO₂QDs was other indispensable reasons for the improved sensor performance. Finally, the ZFSQ-5 composite sensor was attempted to be applied for acetone sensing in exhaled breath, suggesting its great potential in monitoring acetone.