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Updated: Jun 28, 2025
Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
Unlocking single molecule magnetism: a supramolecular strategy for isolating neutral MnIII salen-type dimer in
Yuri Kyoya1, Kiyonori Takahashi1,2, Wataru Kosaka3
1Graduate School of Environmental Science, Hokkaido University, N10W5, Kita-Ward, Sapporo, 060-0810, Japan. ktakahashi@es.hokudai.ac.jp.
Abstract:
In [Mn(5-MeOsalen)(Cl)]2(dibenzo[24]crown-8), dibenzo[24]crown-8 formed a supramolecule via multi-point interactions with the [Mn(5-MeOsalen)(Cl)] dimer. The dimer was magnetically isolated with ST = 4 and weak interdimer magnetic interactions. The crystal exhibited single-molecule magnet behaviour with an anisotropic barrier of 26(1) K, which is the highest among the Mn-salen series reported to date.
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