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Three-Dimensional Epitaxy of Low-Defect 3C-SiC on a Geometrically Modified Silicon Substrate.

Gerard Colston1, Kelly Turner1, Arne Renz1

  • 1School of Engineering, The University of Warwick, Coventry CV4 7AL, UK.

Materials (Basel, Switzerland)
|April 13, 2024
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Summary

We grew cubic silicon carbide (3C-SiC) on compliant substrates, reducing defects by patterning silicon. This method uses standard semiconductor techniques for high-quality 3C-SiC films.

Keywords:
3C-SiCcompliant substrateconformal epitaxyepitaxystacking faults

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Area of Science:

  • Materials Science
  • Semiconductor Physics
  • Crystal Growth

Background:

  • Cubic silicon carbide (3C-SiC) is a promising semiconductor material.
  • Defects in 3C-SiC epilayers hinder device performance.
  • Compliant substrates offer a route to reduce defect density.

Purpose of the Study:

  • To demonstrate the growth of 3C-SiC with reduced planar defects.
  • To investigate defect suppression using micro-scale compliant substrates.
  • To optimize growth conditions for high-quality 3C-SiC epilayers.

Main Methods:

  • Fabrication of micro-scale trenches (2 µm width/separation) in Si(001) substrates.
  • Heteroepitaxial growth of 3C-SiC within these trenches.
  • Hydrogen annealing at 1100 °C and HCl addition during growth.

Main Results:

  • Planar defects were suppressed and channeled away from the 3C-SiC epilayer.
  • Void formation between 3C-SiC columns terminated defects.
  • HCl addition promoted column coalescence into a continuous epilayer.

Conclusions:

  • Micro-scale compliant substrates effectively reduce planar defects in 3C-SiC.
  • The process utilizes standard semiconductor industry techniques.
  • This approach is independent of substrate orientation and offcut.