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What Is the "Hydrogen Bond"? A QFT-QED Perspective
Paolo Renati1,2, Pierre Madl2,3
1World Water Community, NL-3029 Rotterdam, The Netherlands.
International Journal of Molecular Sciences
|April 13, 2024
Summary
The hydrogen bond in water is re-examined using Quantum Electro-Dynamics (QED). This perspective reveals hydrogen bonds as a collective tendency for water molecules to reach a lower energy state, explaining water's anomalous properties.
Area of Science:
- Condensed Matter Physics
- Quantum Electrodynamics (QED)
- Physical Chemistry
Background:
- The traditional view of hydrogen bonds (HB) as simple electrostatic interactions is limited.
- A Quantum Electro-Dynamic (QED) perspective offers a more comprehensive understanding of condensed matter.
- Water's unique properties necessitate a re-evaluation of its fundamental interactions.
Purpose of the Study:
- To reframe the nature of the hydrogen bond (HB) using a non-approximated Quantum Electro-Dynamic (QED) view.
- To explain the anomalous behaviors of water by considering its condensed matter properties.
- To advocate for a transition to Quantum Field Theory (QFT) for a more accurate description of water and living systems.
Main Methods:
- Application of a 40-year-old Quantum Electro-Dynamic (QED) theoretical background.
- Modeling water as a two-fluid system, including a coherent phase.
- Analysis of the electromagnetic field gradient within the coherent phase of water.
Main Results:
- Hydrogen bonds (HB) are reinterpreted as the result of electromagnetic field gradients in water's coherent phase.
- This perspective explains water's collective thermodynamic tendency to occupy a lower ground state.
- The varying energy of hydrogen bonds in different states (dimer, liquid, ice) is accounted for.
Conclusions:
- The traditional "dipolar force" model of hydrogen bonds is insufficient.
- Water's liquid phase at room temperature is a consequence of boson condensation and spontaneous symmetry breaking (SSB).
- A Quantum Field Theory (QFT) approach, or second quantization, is essential for a realistic description of water and condensed matter.
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