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Updated: Jun 28, 2025

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
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Photoinduced decatungstate-catalyzed C(sp3)-H thioetherification by sulfinate salts

Pengcheng Li1, Jia-Lin Tu1, Ao-Men Hu1

  • 1State Key Lab of Urban Water Resource and Environment, School of Science, Harbin Institute of Technology (Shenzhen), Shenzhen, 518055, China. xyyang@hit.edu.cn.

Organic & Biomolecular Chemistry
|April 15, 2024
PubMed

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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