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Updated: Jun 28, 2025

Probing and Mapping Electrode Surfaces in Solid Oxide Fuel Cells
Published on: September 20, 2012
Insight into the effective electrocatalytic sulfide removal from aqueous solutions using surface oxidized
Riying Qi1, Ting Lin1, Kuichuan Sheng1
1College of Biosystems Engineering and Food Science, Zhejiang University, 866 Yuhangtang Road, Hangzhou 310058, China; Key Laboratory of Equipment and Informatization in Environment Controlled Agriculture, Ministry of Agriculture and Rural Affairs, Hangzhou 310058, China; Key Laboratory of Intelligent Equipment and Robotics for Agriculture of Zhejiang Province, Hangzhou 310058, China.
Abstract:
The electrochemical oxidation of hydrogen sulfide (H2S) has shown its potential for the real application of H2S emission control in wastewater treatment. In this study, a surface corrosion treatment of stainless steel (SS) was optimized by regulate Ni content in the oxide film on the SS AISI 304 surface for sulfide removal. The X-ray photoelectron spectroscopy and linear sweeping voltammetry results indicated a higher Ni content in the oxide film of surface-oxidized stainless steel (SOSS) attributed to a higher sulfide removal potential. Sulfide removal experiment results showed that SS-150 (with 150 s anodic pretreatment) anodes achieved the highest Ni content of 69% with the best sulfide removal efficiency, i.e., 97% within 48 h, which increased by 20% compared to the untreated SS. This study also demonstrated a strategy for in situ removal of deposited sulfur on the anodes by cathodic treatment at -0.38 V vs. RHE to alleviate the common issue of sulfur passivation. Density functional theory (DFT) calculation revealed that NiOOH was the major active species in SS-150 oxide film for a faster sulfide removal rate. The study developed a SS surface modification process for Ni content regulation that contributed to better sulfide removal efficiency.
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