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Updated: Jun 28, 2025

Measurement and Analysis of Atomic Hydrogen and Diatomic Molecular AlO, C2, CN, and TiO Spectra Following Laser-induced Optical Breakdown
Published on: February 14, 2014
Bond dissociation energy of O2 measured by fully state-to-state resolved threshold fragment yield spectra
Peng Wang1, Shiyan Gong1, Yuxiang Mo1
1Department of Physics and State Key Laboratory of Low-Dimensional Quantum Physics, Tsinghua University, Beijing 100084, China.
Abstract:
We have determined the bond dissociation energy of O2 by measuring fully state-to-state resolved threshold fragment yield spectra in the XUV energy region, O2X3Σg-,N″,J″→O(PJ3)+O(S1o3)/O(S2o5). Our results have yielded a bond dissociation energy value of 41 269.19 ± 0.10 cm-1, which is consistent with previous measurements but exhibits a significantly lower uncertainty, approximately five times smaller. It is noteworthy that this study is the first to simultaneously achieve fine structure state resolution for the parent O2 molecule and spin-orbit state resolution for the O(3PJ) fragments in the measurement of O2 bond dissociation energy. As a result, our findings have established a solid foundation for the obtained data.
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