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A Novel Method for the Pentosan Analysis Present in Jute Biomass and Its Conversion into Sugar Monomers Using Acidic Ionic Liquid
Published on: June 1, 2018
One pot synthesis of furan-modified lignin from agricultural waste via lignin-first approach
Loku Mannage N Lakmini1, Athukoralage Don K Deshan2, John Bartley2
1Centre for Agriculture and Bioeconomy, School of Chemistry & Physics, Faculty of Science, Queensland University of Technology, George Street, Brisbane, Queensland 4000, Australia.
Abstract:
This study investigated a lignin-first approach to produce furan-modified lignin from sugarcane bagasse (SB), rice hull (RH), and sunn hemp biomass (SHB) using 5 methylfurfural (MF) and 5 methul-2-furanmethanol (MFM). The reaction time (5 h) was selected based on the delignification of SB using methanol and Ru/C catalyst which yielded the highest hydroxyl content. Delignification of SB with various MF weight ratios (1:1, 1:2, 1:3, 2:1, and 3:1) revealed that 1:1 and 2:1 ratios produced the highest hydroxyl content (7.7 mmol/g) and bio-oil yield (23.2 % wt% total weight). Further exploration identified that RH and MF at 1:1 ratio and SHB and MF at a 2:1 ratio produced the highest hydroxyl content (13.0 mmol/g) and bio-oil yield (31.6 % wt% tot. weight). This study developed a one-step method to extract and modify lignin with furan compounds simultaneously while opening new avenues for developing value-added products.
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