Preparation and Characterization of Polyvinyl Alcohol (PVA)/Carbonized Waste Rubber Biocomposite Films

The technological properties of composite materials (thermal, strength, rheology, electrical and morphology) are very important parameters for high-performance applications. In this study, we aimed to improve the properties of PVA by using carbon materials obtained by the pyrolysis of waste tires, with the aim of recycling them instead of disposing of them. For this purpose, PVA biocomposite films containing carbonized waste rubber at different rates were prepared. The thermal properties of the prepared biocomposite films were examined via thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC) methods. While rheological measurements were carried out with a rheometer, bulk conductivities were measured with a pico-ammeter. In addition, the morphology of biocomposite films was determined via field emission scanning electron microscopy. The nanomechanical properties of biocomposite film was investigated via XPM analyses. According to the rheological measurements and nanoindentation hardness results, it is understood that as the amount of carbonized waste rubber increases, flexibility decreases and harder and brittle structures are observed in biocomposite films. The electrical measurement results showed that electrical conductivity increased as the amount of carbonized waste rubber increased. When all the results obtained were evaluated, it could be concluded that biocomposite films obtained by increasing the electrical conductivity and hardness of PVA can be used in the electronics industry.