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Updated: Jun 27, 2025

Synthesis of Near-Infrared Emitting Gold Nanoclusters for Biological Applications
Published on: March 22, 2020
Green Synthetic Approach for the Preparation of Blue Emitting Gold Nanoclusters: A Simple Analytical Method for
Vibhuti Atulbhai Sadhu1, Sanjay Jha2, Vaibhavkumar N Mehta2
1Department of Chemistry, Sardar Vallabhbhai National Institute of Technology, Surat, 395 007, Gujarat, India.
Abstract:
Blue emissive Argyreia nervosa-capped gold nanoclusters (A. nervosa-AuNCs) were synthesized via a simple environment-friendly method. The developed probe exhibits rapid response towards the target analyte (hexaconazole fungicide). Several characterizations, including FT-IR, UV-visible, fluorescence, HR-TEM, XPS, and fluorescence lifetime, were studied to confirm the formation of A. nervosa-AuNCs. The A. nervosa-AuNCs displayed emission and excitation peaks at 470 and 390 nm, respectively. Furthermore, the quantum yield (QY) of A. nervosa-AuNCs was 21.25%. The as-synthesized A. nervosa-AuNCs showed a good linear response with hexaconazole in the concentration range of 0.025-180 μM, with a detection limit (LOD) of 21.94 nM, indicating A. nervosa-AuNCs could be used as a sensitive and selective probe for detecting hexaconazole through a fluorescence "turn-off" mechanism. The A. nervosa-AuNCs were successfully used to detect hexaconazole in real samples. Moreover, A. nervosa-AuNCs were used as a bio-imaging probe for visualization of Saccharomyces cerevisiae cells.

