ZnMo-MOF as anti-CO hydrogen electrocatalyst enhance microbial electrosynthesis for CO/CO₂ conversion

Microbial electrosynthesis (MES) is an electrically driven technology that can be used for converting CO/CO₂ into chemicals. The unique electronic and substrate properties of CO make it an important research target for MES. However, CO can poison the cathode and increase the overpotential of hydrogen evolution reaction (HER), thus reducing the electron transfer rate via H₂. This work evaluated the effect of an anti-CO HER catalyst on the performance of MES for CO/CO₂ conversion. ZnMo-metal-organic framework (MOF) materials with different calcination temperatures were synthesized. ZnMo-MOF-800 with Mo₂C nanoparticles as active centers exhibited excellent resistance to CO toxicity. It also obtained the highest hydrogen evolution and enhanced electron transfer rate in CO atmosphere. MES with ZnMo-MOF-800 cathode and Clostridium ljungdahlii as biocatalyst obtained 0.31 g L^-1 d^-1 acetate yield, 0.1 g L^-1 d^-1 butyrate yield, and 0.09 g L^-1 d^-1 2,3-butanediol yield in CO/CO₂, while Pt/C only get 0.076 g L^-1 d^-1 acetate yield, 0.05 g L^-1 d^-1 butyrate yield and 0.02 g L^-1 d^-1 2,3-butanediol yield. ZnMo-MOF-800 was conducive to biofilm formation, enabling it to better resist CO toxicity. This work provides new opportunities for constructing a highly efficient cathode with an anti-CO hydrogen evolution catalyst to enhance CO/CO₂ conversion in MES.