Recent advances in alginate-based composite gel spheres for removal of heavy metals

The discharge of heavy metal ions from industrial wastewater into natural water bodies is a consequence of global industrialisation. Due to their high toxicity and resistance to degradation, these heavy metal ions pose a substantial threat to human health as they accumulate and amplify. Alginate-based composite gels exhibit good adsorption and mechanical properties, excellent biodegradability, and non-toxicity, making them environmentally friendly heavy metal ion adsorbents for water with promising development prospects. This paper introduces the basic properties, cross-linking methods, synthetic approaches, modification methods, and manufacturing techniques of alginate-based composite gels. The adsorption properties and mechanical strength of these gels can be enhanced through surface modification, multi-component mixing, and embedding. The main production processes involved are sol-gel and cross-linking methods. Additionally, this paper reviews various applications of alginate composite gels for common heavy metals, rare earth elements, and radionuclides and elucidates the adsorption mechanism of alginate composite gels. This study aimed to provide a reference for synthesising new, efficient, and environmentally friendly alginate-based adsorbents and to contribute new ideas and directions for addressing the issue of heavy metal pollution.