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Updated: Jun 27, 2025
Synthesis and Characterization of Amphiphilic Gold Nanoparticles
Published on: July 2, 2019
A Gold(I)-Acetylene Complex Synthesised using Single-Crystal Reactivity
Chloe L Johnson1, Daniel J Storm2, M Arif Sajjad2
1Department of Chemistry, University of York, York, YO10 5DD, UK.
Abstract:
Using single-crystal to single-crystal solid/gas reactivity the gold(I) acetylene complex [Au(L1)(η2-HC≡CH)][BArF 4] is cleanly synthesized by addition of acetylene gas to single crystals of [Au(L1)(CO)][BArF 4] [L1=tris-2-(4,4'-di-tert-butylbiphenyl)phosphine, ArF=3,5-(CF3)2C6H3]. This simplest gold-alkyne complex has been characterized by single crystal X-ray diffraction, solution and solid-state NMR spectroscopy and periodic DFT. Bonding of HC≡CH with [Au(L1)]+ comprises both σ-donation and π-backdonation with additional dispersion interactions within the cavity-shaped phosphine.
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