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It is essential to understand the difference between chiral and achiral interactions and the implications thereof in optical activity and their applications. Just as our feet, which are chiral, interact uniquely with chiral objects, such as a pair of shoes, but identically with achiral socks, enantiomers of a molecule exhibit different properties only when they interact with other chiral media. An example of a significant implication from this facet is the phenomenon known as optical activity,...
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Molecules that possess multiple chiral centers can afford a large number of stereoisomers. For instance, while some molecules like 2-butanol have one chiral center, defined as a tetrahedral carbon atom with four different substituents attached, several molecules like butane-2,3-diol have multiple chiral centers. A simple formula to predict the number of stereoisomers possible for a molecule with n chiral centers is 2n. However, there can be a lower number where some of the stereoisomers are...
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A racemic mixture, or racemate, is an equimolar mixture of enantiomers of a molecule that can be separated using their unique interaction with chiral molecules or media. Racemic mixtures are denoted by the (±)- prefix. This ‘optical rotation descriptor’ applies to the whole solution of a racemic mixture rather than a specific stereoisomer. Enantiomers typically have the same physical and chemical properties. Hence, they are not easily separable. However, enantiomers can exhibit...
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Nonreciprocity and odd viscosity in chiral active fluids.

Tomer Markovich1,2, Tom C Lubensky3

  • 1School of Mechanical Engineering, Tel Aviv University, Tel Aviv 69978, Israel.

Proceedings of the National Academy of Sciences of the United States of America
|May 3, 2024
PubMed
Summary

Odd viscosity in chiral active matter breaks Onsager reciprocal relations due to angular momentum density. This leads to new mechanical waves and potential nonreciprocal phase transitions.

Keywords:
active matterchiral active matternonequilibrium statistical mechanicsnonreciprocal active matterodd viscosity

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Area of Science:

  • Condensed matter physics
  • Active matter physics
  • Fluid dynamics

Background:

  • Odd viscosity couples stress and strain rate dissipationlessly.
  • Previously studied in plasmas, superfluids, and quantum-Hall fluids, often obeying Onsager reciprocal relations.
  • Its behavior in active materials, particularly chiral active matter, remains less understood.

Purpose of the Study:

  • To investigate whether Onsager reciprocal relations hold for odd viscosity in chiral active matter.
  • To explore the consequences of breaking these relations on material dynamics.
  • To identify conditions for the propagation of odd mechanical waves and mechanical instabilities.

Main Methods:

  • Direct coarse-graining of kinetic energy.
  • Application of the Poisson-bracket formalism.
  • Kinetic theory derivation.

Main Results:

  • Nonvanishing angular momentum density in chiral active matter breaks Onsager reciprocal relations.
  • This results in a non-Hermitian dynamical matrix and odd viscosity.
  • Identified regions for 3D odd mechanical wave propagation and mechanical instability, separated by exceptional points.

Conclusions:

  • Angular momentum density is key to breaking Onsager relations in active matter.
  • Odd viscosity and non-Hermitian dynamics arise from this breaking.
  • The findings suggest a possible nonreciprocal phase transition in chiral active materials.