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Phase Transitions: Melting and Freezing02:39

Phase Transitions: Melting and Freezing

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Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
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Polymer Classification: Crystallinity01:21

Polymer Classification: Crystallinity

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Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
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Phase Transitions: Sublimation and Deposition02:33

Phase Transitions: Sublimation and Deposition

17.1K
Some solids can transition directly into the gaseous state, bypassing the liquid state, via a process known as sublimation. At room temperature and standard pressure, a piece of dry ice (solid CO2) sublimes, appearing to gradually disappear without ever forming any liquid. Snow and ice sublimate at temperatures below the melting point of water, a slow process that may be accelerated by winds and the reduced atmospheric pressures at high altitudes. When solid iodine is warmed, the solid sublimes...
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Cryo-electron Microscopy01:28

Cryo-electron Microscopy

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Conventional electron microscopy (EM) involves dehydration, fixation, and staining of biological samples, which distorts the native state of biological molecules and results in several artifacts. Also, the high-energy electron beam damages the sample and makes it difficult to obtain high-resolution images. These issues can be addressed using cryo-EM, which uses frozen samples and gentler electron beams. The technique was developed by Jacques Dubochet, Joachim Frank, and Richard Henderson, for...
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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

17.1K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Sublimation01:03

Sublimation

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Sublimation is the direct transformation of a solid to a gaseous state. For instance, at standard pressure and room temperature, solid carbon dioxide sublimes to gaseous carbon dioxide. The phase diagram depicts the conditions required for sublimation. This process occurs at the solid-gas phase boundary and is not observed above the triple point of the substance. The reverse of sublimation is called deposition, where a gaseous substance condenses directly into a solid. Sublimation and...
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Related Experiment Video

Updated: Jun 26, 2025

A Microfluidic Approach for the Study of Ice and Clathrate Hydrate Crystallization
08:01

A Microfluidic Approach for the Study of Ice and Clathrate Hydrate Crystallization

Published on: August 18, 2022

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Flash melting amorphous ice.

Nathan J Mowry1, Constantin R Krüger1, Gabriele Bongiovanni1

  • 1Ecole Polytechnique Fédérale de Lausanne (EPFL), Laboratory of Molecular Nanodynamics, CH-1015 Lausanne, Switzerland.

The Journal of Chemical Physics
|May 9, 2024
PubMed
Summary
This summary is machine-generated.

Researchers discovered that flash melting amorphous ice with lasers causes it to crystallize, even at rapid heating rates. This contrasts with rapid cooling, which achieves vitrification, offering new insights into water

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Area of Science:

  • Physical Chemistry
  • Materials Science
  • Biophysics

Background:

  • Water can be vitrified (formed into glass) by rapid cooling, avoiding crystallization in the 'no man's land' of deeply supercooled states.
  • Understanding water's behavior in this supercooled regime is crucial for various scientific fields, including cryo-electron microscopy.

Purpose of the Study:

  • To investigate the reverse process of vitrification: flash melting of amorphous ice using microsecond laser pulses.
  • To elucidate the crystallization mechanisms of water under extreme heating conditions.

Main Methods:

  • Flash melting of pure water samples (amorphous ice) using high-power microsecond laser pulses.
  • Time-resolved electron diffraction to observe structural changes during and after laser heating.
  • Comparison of crystallization kinetics between amorphous solid water and hyperquenched glassy water.

Main Results:

  • Transient crystallization of water was observed despite extremely high heating rates (> 5 × 10^6 K/s).
  • This crystallization occurred even though similar cooling rates (10^7 K/s) can achieve vitrification.
  • Distinct crystallization kinetics were identified for different forms of amorphous ice.

Conclusions:

  • The study reveals unexpected crystallization behavior during rapid laser-induced melting of amorphous ice.
  • Findings challenge assumptions about water's phase transitions and provide new data on its dynamics in 'no man's land'.
  • These results are vital for advancing microsecond time-resolved cryo-electron microscopy techniques.