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Reviewing the effect of aggregates in Rhodamine 6G aqueous solution on fluorescence quantum efficiency.

U Rocha1, L E G Armas2, W F Silva1

  • 1Group of Nano-Photonics and Imaging, Instituto de Física, Universidade Federal de Alagoas, 57072-900 Maceió, AL, Brazil.

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Aggregation significantly impacts Rhodamine 6G (R-6G) dye properties. A new model reveals dimer contributions to fluorescence quantum efficiency (η), crucial for understanding energy transfer (ET) at high concentrations.

Keywords:
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Area of Science:

  • Photochemistry
  • Materials Science
  • Spectroscopy

Background:

  • Rhodamine 6G (R-6G) is a highly luminescent dye widely used in various applications.
  • Dye aggregation can alter optical and thermal properties, impacting performance.
  • Understanding these changes is crucial for optimizing dye applications.

Purpose of the Study:

  • To investigate the effect of aggregation on Rhodamine 6G (R-6G) solutions in water.
  • To analyze thermal diffusivity, refractive index temperature coefficient, fluorescence quantum efficiency, and energy transfer.
  • To develop a novel model for heat conversion accounting for monomer and dimer contributions.

Main Methods:

  • Utilized thermal lens (TL) spectroscopy.
  • Employed conventional absorption and emission spectroscopy.
  • Applied Förster theory for energy transfer (ET) calculations.

Main Results:

  • R-6G concentration affects absorption and emission spectra due to dimer formation, influencing fluorescence quantum efficiency (η).
  • A new model for the fraction of absorbed energy converted into heat (φ) was introduced.
  • Monomer fluorescence quantum efficiency (ηm) necessitates a significant dimer contribution (ηd = 0.2).
  • Energy transfer microparameters (CDD, CDA) were calculated, indicating significant monomer-monomer and monomer-dimer ET.

Conclusions:

  • Dimerization significantly influences R-6G's optical and thermal properties.
  • The novel heat conversion model accurately captures monomer and dimer effects.
  • Energy transfer processes are critical for understanding R-6G behavior, especially at high concentrations.
  • Findings are relevant for R-6G in water and suggest similar studies in other aggregated dye systems.