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Updated: Jun 26, 2025

Manufacturing Simple and Inexpensive Soil Surface Temperature and Gravimetric Water Content Sensors
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Modeled versus Experimental Salt Mixture Behavior under Variable Humidity.

Sebastiaan Godts1,2,3, Michael Steiger4, Amelie Stahlbuhk4

  • 1Monuments Lab, Royal Institute for Cultural Heritage (KIK-IRPA), Brussels 1000, Belgium.

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|May 13, 2024
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Summary

This study reveals how salt mixture crystallization and dissolution kinetics are affected by relative humidity (RH) changes. Rapid RH fluctuations significantly alter salt behavior compared to thermodynamic models, impacting stone decay and heritage preservation.

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Area of Science:

  • Environmental Science
  • Geology
  • Materials Science
  • Heritage Science

Background:

  • Salt mixtures are prevalent in geological formations and built heritage.
  • Understanding salt crystallization and dissolution is crucial for predicting material decay and informing preservation strategies.
  • Previous studies often simplified the complex interplay between salt composition, relative humidity, and environmental dynamics.

Purpose of the Study:

  • To investigate the kinetics of salt mixture crystallization and dissolution under varying relative humidity (RH) conditions.
  • To determine the influence of RH change rates on salt phase transitions and crystal habit.
  • To validate thermodynamic models against experimental observations for diverse salt mixtures.

Main Methods:

  • Utilized time-lapse microscopy and dynamic vapor sorption to monitor salt behavior.
  • Employed environmental scanning electron microscopy (ESEM) for microstructural analysis.
  • Confirmed predicted salt phases using micro-Raman spectroscopy, X-ray diffraction (XRD), and energy-dispersive X-ray spectroscopy (EDX).

Main Results:

  • Observed significant deviations in crystallization (-15%) and dissolution (+7%) kinetics from thermodynamic models under rapid RH changes.
  • Established a strong correlation between the rate of RH change and the kinetics of salt phase transitions.
  • Identified specific crystal habits corresponding to RH transitions through microstructural analysis.

Conclusions:

  • The rate of relative humidity change critically influences salt crystallization and dissolution kinetics, deviating from equilibrium predictions.
  • These findings are vital for accurate modeling of salt weathering, stone decay in built heritage, and geological salt processes.
  • Provides essential data for developing effective preservation strategies and refining predictive models in environmental and geological sciences.