Optimizing anisotropic transport on bioinspired sawtooth surfaces

Species ranging from butterflies and other insects, to cactuses and lotus plants have evolved to use geometrically patterned surfaces to influence the transport of water droplets. While this phenomenon is well known, an ideal geometry has yet to be discovered. To determine the impact of surface geometry on droplet transport, we have studied the contact angle and droplet motion across anisotropically wetting patterned surfaces. The surface geometries tested were sawtooth patterns with angles (8.62-26.70°) and lengths (0.56-1.67 μm). The droplet contact angles were measured on 45° angled surfaces to simulate the droplet in motion. Velocities were measured using a high-speed camera shooting at 500 frames per second and the tailing edges of the droplets were hand tracked over 18 frames. It was found that travel along the sawtooth ridges is significantly faster than travel against the ridges for geometries with shallow angles. The optimal geometry was determined to be α = 8.62° and b = 1.67 μm and was replicated using nanoimprint lithography using materials with different surface energies. When replicated with acrylate resins and PDMS, the contact angles remained high, regardless of wettability, but we find that the overall velocity and velocity hysteresis depends on the hydrophobicity. More hydrophobic surfaces have overall higher hysteresis. The ability to tune imprinted surfaces to achieve ideal wetting characteristics using geometry will lead to interesting anisotropic material design.