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Related Concept Videos

Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)01:20

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Two NMR-active nuclei bonded to a central atom can be involved in geminal or two-bond coupling. Geminal coupling is commonly seen between diastereotopic protons in chiral molecules and unsymmetrical alkenes, among others.
The central atom need not be NMR-active because its electrons are affected by the electron polarization of the spin-active atoms. However, spin information is transmitted less effectively than in one-bond coupling, and 2J values are usually weaker than 1J values. The energy of...
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Updated: Jun 26, 2025

Investigating Single Molecule Adhesion by Atomic Force Spectroscopy
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Single-Spin Sensing: A Molecule-on-Tip Approach.

Alex Fétida1, Olivier Bengone1, Michelangelo Romeo1

  • 1Université de Strasbourg, CNRS, IPCMS, UMR 7504, F-67000 Strasbourg, France.

ACS Nano
|May 13, 2024
PubMed
Summary
This summary is machine-generated.

Researchers developed a new atomic-scale magnetic imaging technique using a nickelocene molecule and scanning tunneling microscopy. This method provides high-resolution spin-sensitive imaging of magnetic surfaces, advancing ultradense storage technology.

Keywords:
density functional theorynickelocenescanning tunneling microscopysingle spinsurface magnetismtip functionalization

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Area of Science:

  • Materials Science
  • Surface Science
  • Quantum Technologies

Background:

  • Magnetometry is crucial for ultradense storage and downscaled spin qubits.
  • Atomic-scale single-spin sensing using magnetic molecules is an emerging but challenging field.

Purpose of the Study:

  • To demonstrate a novel method for atomic-scale spin-sensitive imaging of magnetic surfaces.
  • To investigate the potential of using a nickelocene molecule with scanning tunneling microscopy for magnetic sensing.

Main Methods:

  • Combined a nickelocene-terminated scanning tunneling microscopy tip with magnetic surfaces.
  • Investigated model Cobalt (Co) islands on Copper (Cu)(111) with varying magnetic properties.
  • Performed spin-sensitive imaging and analyzed magnetic exchange coupling.

Main Results:

  • Achieved atomic-scale sensitivity to spin polarization and magnetization orientation.
  • Demonstrated robustness and reproducibility of the spin-sensitive imaging technique.
  • Generated magnetic exchange maps revealing unique signatures in magnetic corrugation.

Conclusions:

  • The nickelocene-based scanning tunneling microscopy technique offers a powerful new tool for atomic-level magnetism visualization.
  • This advancement enhances the capability to probe and understand magnetic phenomena at the nanoscale.
  • The method shows promise for applications in ultradense storage and quantum information processing.