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Programming Positive Mechanofluorescence in Liquid Crystalline Elastomers.

Pedro Güixens-Gallardo1,2, Ignacio Brea1, Jordi Manrique1

  • 1Grup de Materials Orgànics, Departament de Química Inorgànica i Orgànica (Secció de Química Orgànica), Universitat de Barcelona, Martí i Franquès 1, E-08028 Barcelona, Spain.

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Summary
This summary is machine-generated.

Researchers developed novel liquid single crystal elastomers (LSCEs) that exhibit positive mechanofluorescence, meaning their light emission increases under mechanical stress. This breakthrough, achieved using fluorescent molecular rotors, offers a new way to detect forces with smart materials.

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Spectroscopy

Background:

  • Liquid single crystal elastomers (LSCEs) with embedded organic fluorophores are used for force detection via spectroscopy.
  • Existing LSCEs show negative mechanofluorescence (decreased emission under stress) due to quenching effects.
  • This phenomenon is caused by mechanically induced proximity of quenching mesogenic units and fluorophores.

Purpose of the Study:

  • To develop LSCEs with positive mechanofluorescence (increased emission under stress).
  • To integrate fluorescent molecular rotors (FMRs) into LSCEs for enhanced force sensing capabilities.
  • To design elastomeric materials with tunable mechano-optical responses.

Main Methods:

  • Incorporation of fluorescent molecular rotors (FMRs), specifically carbazole-indolenine dyes, into the LSCE network.
  • Utilizing FMRs whose luminescence is independent of mesogenic quenching.
  • Applying uniaxial deformation along the anisotropic direction of the LSCE.

Main Results:

  • Demonstrated positive mechanofluorescence in LSCEs containing FMRs.
  • Observed enhanced luminescence emission upon mechanical deformation.
  • Established a correlation between restricted local environment and increased fluorescence intensity.

Conclusions:

  • Fluorescent molecular rotors offer a viable strategy for creating positive mechanofluorescence in LSCEs.
  • LSCEs with FMRs provide a novel platform for advanced force-sensing applications.
  • The observed phenomenon opens new avenues for designing smart materials with tailored mechano-optical properties.