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Updated: Jun 26, 2025

A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis
Published on: February 16, 2020
Photocatalytic α-arylation of cyclic ketones by a thermally activated delayed fluorescence molecule
Baishanal Mandal1, Sourav Mandal1, Supriya Halder1
1Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Mohali, Sector-81, Knowledge City, Manauli-140306, India. adhikari@iisermohali.ac.in.
Abstract:
α-Arylation of cyclic ketones via an organophotocatalytic route has been described utilizing PXZ-TRZ, a molecule displaying thermally activated delayed fluorescence (TADF). Using this route, a plethora of cyclic ketones including cyclohexanone, cyclopentanone and even cyclooctanone can be effectively arylated with many aryl iodides or bromides under mild conditions.
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