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Published on: April 2, 2015
Colloid Transport in Bicontinuous Nanoporous Media
Aoyan Liang1, Chang Liu1, Paulo S Branicio1
1Mork Family Department of Chemical Engineering and Materials Science, University of Southern California, Los Angeles, California 90089-0242, United States.
Colloid transport in nanoporous media is governed by straining and trapping. Higher colloid concentration and attraction to media increase retention, potentially causing clogging.
Area of Science:
- Earth Science
- Nanotechnology
- Fluid Dynamics
Background:
- Colloid transport and retention are crucial in Earth science applications like groundwater remediation and oil recovery.
- Nanoporous media present unique challenges due to boundary layer effects and nanoconfinement altering colloid behavior.
Purpose of the Study:
- To simulate colloid transport and retention in bicontinuous nanoporous (BNP) media using particle dynamics models.
- To elucidate colloid retention mechanisms and investigate the influence of key factors on colloid transport.
Main Methods:
- Utilized particle dynamics models to simulate colloid transport in BNP media under pressure gradients.
- Tracked individual colloid movement to identify retention mechanisms and analyzed breakthrough curves.
Main Results:
- Identified physical straining and trapping in low-flow zones as primary retention mechanisms under unfavorable conditions.
- Higher colloid volume fraction (d), lower pressure difference (ΔP), and strong colloid-media attraction (Ec-p) increase retention, leading to clogging.
- Colloid-colloid interactions (Ec-c) showed minimal impact due to confined nanoporous channels.
Conclusions:
- Fundamental factors governing colloid transport and retention in stochastic nanoporous materials have been identified.
- Understanding these factors is critical for optimizing processes in groundwater remediation and enhanced oil recovery.
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