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Atomic Molybdenum Nanomaterials for Electrocatalysis.

Jianmei Chen1, Shanlu Guo1, Longlu Wang1

  • 1College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing, 210023, China.

Small (Weinheim an Der Bergstrasse, Germany)
|May 17, 2024
PubMed
Summary
This summary is machine-generated.

Molybdenum single-atom catalysts (Mo-SACs) offer high performance for sustainable energy applications. This review highlights their synthesis, microenvironment engineering, and applications in N2, H2O, and CO2 electrocatalytic conversions.

Keywords:
coordination modulationelectrocatalysismolybdenum‐based nanomaterialssingle‐atom catalystsstructural engineering

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Sustainable Energy

Background:

  • Electrocatalytic energy conversion is crucial for sustainable technologies.
  • Nonprecious metal electrocatalysts, particularly molybdenum-based nanomaterials, show great promise.
  • Mo-based single-atom catalysts (Mo-SACs) offer accessible active sites and tunable microenvironments.

Purpose of the Study:

  • To provide a timely review of recent advances in Mo-SACs.
  • To guide further exploration of optimized Mo-SACs for electrochemical energy technologies.
  • To highlight synthetic strategies and microenvironment engineering of Mo atoms.

Main Methods:

  • Review of recent synthetic strategies for Mo-SACs.
  • Focus on microenvironment engineering of Mo atoms.
  • Combination of experimental and computational results for application analysis.

Main Results:

  • Recent advances in Mo-SAC synthesis and microenvironment engineering are highlighted.
  • Mo-SACs demonstrate significant achievements in N2, H2O, and CO2 electrocatalytic reactions.
  • Experimental and computational data support the efficacy of Mo-SACs.

Conclusions:

  • Mo-SACs are promising catalysts for various electrochemical conversion reactions.
  • Further research is needed to optimize Mo-SACs for enhanced electrocatalysis.
  • Key challenges and future prospects for Mo-SAC development are identified.