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Strong Acceptors Based on Derivatives of Benzothiadiazoloimidazole
Hanyun Du1, Bin Chen2, Fengyuan Zhang2
1School of Material Science and Chemical Engineering, Ningbo University, Ningbo 315211, China.
Abstract:
Despite the rapid progression of organic semiconductors, developing high-air-stability n-type organic semiconductors are still challenging. Herein, novel strong acceptors based on benzothiadiazoloimidazole units are reported. The results reveal that the strong acceptor BTI-NDI-BTI-a has good solubility and high electron affinity (3.94 eV), accompanied by 1D slipped-stacking crystals. Notably, the material presents promising potential for developing into air-stable n-type organic semiconductor materials.
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