Interfacial Design of Particulate Photocatalyst Materials for Green Hydrogen Production

Green hydrogen production using particulate photocatalyst materials has attracted much attention in recent years because this process could potentially lead to inexpensive and scalable solar-to-chemical energy conversion systems. Although the development of efficient particulate photocatalysts enabling one-step overall water splitting (OWS) with solar-to-hydrogen efficiencies in excess of 10 % remains challenging, promising photocatalyst candidates exhibiting OWS activity have been demonstrated. This review provides a comprehensive introduction to the solar-to-hydrogen energy conversion process of semiconductor photocatalyst materials and highlights recent advances in photocatalytic OWS via both one-step and two-step photoexcitation processes. The review also covers recent developments in the photocatalytic OWS of SrTiO₃, including the establishment of large-scale photocatalytic systems, interfacial design using cocatalysts to enhance water splitting activity, and its photoelectrochemical (PEC) properties at the electrified solid/liquid interface. In addition, there is a special focus on visible-light-absorbing oxynitride and oxysulfide particulate photocatalysts with absorption edges near 600 nm. Methods for photocatalyst preparation and surface modification, as well as PEC properties, are also discussed. The semiconductor properties of particulate photocatalysts obtained from photoelectroanalytical evaluations using particulate photoelectrodes are evaluated. This review is intended to provide guidelines for the future development of particulate photocatalysts capable of efficient and stable OWS.