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Updated: Jun 25, 2025

Fluid-cell Raman Spectroscopy for operando Studies of Reaction and Transport Phenomena during Silicate Glass Corrosion
Published on: May 9, 2025
Comprehensive analysis of the corrosion behavior of UG1 phosphate-based ultraviolet glass in water environments
Xianpeng Liang1, Quan Yuan1, Peng Gao1
1Shenyang Academy of Instrumentation Science CO.,LTD., Shenyang, 110043, China.
Abstract:
We herein delve into the corrosion dynamics of UG1 in high-temperature water, employing thermal acceleration to expedite reactions. Corrosion-induced changes in spectral properties, optical constants, and morphology are analyzed. The results reveal a phosphorus-poor layer near the surface that affects transmittance, refractive index, and extinction coefficient, with corrosion rates following a parabolic model. This study provides crucial insights for protecting UG1 in humid environments and emphasizes the importance of implementing protective measures against phosphorus diffusion.
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