Recent advances and mechanism of plasmonic metal-semiconductor photocatalysis

Benefiting from the unique surface plasmon properties, plasmonic metal nanoparticles can convert light energy into chemical energy, which is considered as a potential technique for enhancing plasmon-induced semiconductor photocatalytic reactions. Due to the shortcomings of large bandgap and high carrier recombination rate of semiconductors, their applications are limited in the field of sustainable and clean energy sources. Different forms of plasmonic nanoparticles have been reported to improve the photocatalytic reactions of adjacent semiconductors, such as water splitting, carbon dioxide reduction, and organic pollutant degradation. Although there are various reports on plasmonic metal-semiconductor photocatalysis, the related mechanism and frontier progress still need to be further explored. This review provides a brief explanation of the four main mechanisms of plasmonic metal-semiconductor photocatalysis, namely, (i) enhanced local electromagnetic field, (ii) light scattering, (iii) plasmon-induced hot carrier injection and (iv) plasmon-induced resonance energy transfer; some related typical frontier applications are also discussed. The study on the mechanism of plasmonic semiconductor complexes will be favourable to develop a new high-performance semiconductor photocatalysis technology.