A Comprehensive Review on Strategies for Enhancing the Performance of Polyanionic-Based Sodium-Ion Battery Cathodes

The significant consumption of fossil fuels and the increasing pollution have spurred the development of energy-storage devices like batteries. Due to their high cost and limited resources, widely used lithium-ion batteries have become unsuitable for large-scale energy production. Sodium is considered to be one of the most promising substitutes for lithium due to its wide availability and similar physiochemical properties. Designing a suitable cathode material for sodium-ion batteries is essential, as the overall electrochemical performance and the cost of battery depend on the cathode material. Among different types of cathode materials, polyanionic material has emerged as a great option due to its higher redox potential, stable crystal structure, and open three-dimensional framework. However, the poor electronic and ionic conductivity limits their applicability. This review briefly discusses the strategies to deal with the challenges of transition-metal oxides and Prussian blue analogue, recent developments in polyanionic compounds, and strategies to improve electrochemical performance of polyanionic material by nanostructuring, surface coating, morphology control, and heteroatom doping, which is expected to accelerate the future design of sodium-ion battery cathodes.