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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
A novel Cu(I)-based coordination polymer for efficient photocatalytic oxidation of C(sp3)-H bonds
Jiangtao Deng1, Huilin Huang1, Zhentao Li1
1State Key Laboratory of Fine Chemicals, College of Chemistry, Dalian University of Technology, 116024, P. R. China. xjing@dlut.edu.cn.
Abstract:
A novel coordination polymer CuCl-Pyhc was successfully synthesized, which can catalyze efficient and selective oxidation of C(sp3)-H bonds under mild conditions, exhibiting exceptional stability and remarkable recyclability. Furthermore, CuCl-Pyhc can mimic natural monooxygenases and activate oxygen into singlet oxygen (1O2).
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