Controllable fabrication of Sb_xBi_2-xS₃ solid solution photocatalysts with superior elimination for Cr(VI)

The development of environmentally friendly and cost-effective photocatalysts is of vital significance for the effective removal of heavy metal contamination in water, but it is still a crucial challenge. Herein, the novel Sb_xBi_2-xS₃ solid solution photocatalysts with a certain amount of sulfur vacancy were prepared by adjusting the molar ratio of Sb to Bi through a simple hydrothermal strategy, and was applied to the effective photocatalytic reduction of hexavalent chromium (Cr(VI)). Sb_1.75Bi_0.25S₃ with optimized ratio has superior reduction performance of Cr(VI), and the photocatalytic efficiency of Cr(VI) can achieve 91.9 % within 1 h of visible light illumination. The remarkable catalytic efficiency is due to the more applicable band structure of the solid solution photocatalyst, which is conducive for the photocatalytic reaction. Moreover, the substitution of Bi causes the crystal distortion of Sb₂S₃ and induce the generation of sulfur defects, which can effectively capture photoelectrons, accelerate the carriers separation, and improve the reduction performance. This study provides a hopeful photocatalyst for wastewater purification and promotes the exploration of solid solution photocatalyst in water environment remediation.