Modified Expression for the Hamiltonian Expectation Value Exploiting the Short-Range Behavior of the Wave Function

The expectation value of the Hamiltonian using a model wave function is widely used to estimate the eigenvalues of electronic Hamiltonians. We explore here a modified formula for models based on a long-range interaction. It scales differently the singlet and triplet components of the repulsion between electrons not present in the model (its short-range part). The scaling factors depend uniquely on the parameter used in defining the model interaction and are constructed using only exact properties. We show results for the ground states and low-lying excited states of Harmonium with two to six electrons. We obtain important improvements for the estimation of the exact energy, not only over the model energy but also over the expectation value of the Hamiltonian.