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![[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Non-coordinating counteranion as a powerful tool to tune the activity of copper water oxidation catalysts
Xin Li1, Lijuan Wang1, Mengjiao Shao1
1School of Materials and Chemistry, University of Shanghai for Science and Technology, 516 Jungong Rd., Shanghai 200093, China. leiwang@usst.edu.cn.
Abstract:
Ten copper-bipyridine-type catalysts, [(bpyR)Cu(OH)2]2+, featuring diverse counteranions (OAc-, Cl-, SO42-, NO3-, OTf-) were synthesized. The observed substantial variations in turnover frequency (TOF) among these catalysts, coupled with insights gained from electrochemical investigations, underscore the pivotal influence of counteranions in fine-tuning the catalytic activity of metal complexes during water oxidation. The TOF value follows the trend of OAc- > Cl- > SO42- > NO3- > OTf-, which is the same as the change of coordinating ability index, a™. Density Functional Theory (DFT) calculations reveal that counteranion coordination plays an important role in influencing the catalytic performance of these complexes.
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