Enhancing Circularly Polarized Electroluminescence through Energy Transfer within a Chiral Polymer Host

Organic light-emitting diodes (OLEDs) that are able to emit high levels of circularly polarized (CP) light hold significant promise in numerous future technologies. Such devices require chiral emissive materials to enable CP electroluminescence. However, the vast majority of current OLED emitter classes, including the state-of-the-art triplet-harvesting thermally activated delayed fluorescence (TADF) materials, produce very low levels of CP electroluminescence. Here a host-guest strategy that allows for energy transfer between a chiral polymer host and a representative chiral TADF emitter is showcased. Such a mechanism results in a large amplification of the circular polarization of the emitter. As such, this study presents a promising avenue to further boost the performance of circularly polarized organic light-emitting diode devices, enabling their further development and eventual commercialization.