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Enabling Gradient-Structured Solid Electrolyte Interphase by a Hydrated Eutectic Electrolyte for High-Performance Zn

Ming Li1, Xiaonan Zhu1, Chenxu Jiang1

  • 1School of Environmental and Chemical Engineering, Shanghai University, Shanghai, 200444, China.

Small (Weinheim an Der Bergstrasse, Germany)
|June 14, 2024
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Summary
This summary is machine-generated.

A novel hydrated eutectic electrolyte (HEE) prevents side reactions and dendrite growth in aqueous zinc metal anodes (ZMAs), enabling stable battery cycling. This advance enhances safety and longevity for next-generation energy storage systems.

Keywords:
SEIZn metal batteriesgradient structurehydrated eutectic electrolytesolvation sheath

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Area of Science:

  • Electrochemistry
  • Materials Science
  • Energy Storage

Background:

  • Aqueous zinc metal batteries (ZMAs) offer safe and cost-effective energy storage.
  • However, ZMA performance is limited by water-induced parasitic reactions and dendrite growth.

Purpose of the Study:

  • To develop a novel hydrated eutectic electrolyte (HEE) for improved ZMA reversibility and cyclability.
  • To investigate the role of sulfolane and Zn(BF4)2 in stabilizing the electrolyte and anode interface.

Main Methods:

  • Formulation of a hydrated eutectic electrolyte (HEE) using Zn(BF4)2·xH2O and sulfolane (SL).
  • Electrochemical characterization of Zn||Zn symmetric cells and Zn||NH4V4O10 full cells.
  • Analysis of the electrolyte's solvation structure and the solid electrolyte interphase (SEI) composition.

Main Results:

  • The HEE demonstrated stable cycling of Zn||Zn symmetric cells for over 1650 hours.
  • Zn||NH4V4O10 full batteries exhibited a lifespan of 1000 cycles with 83.4% capacity retention.
  • The HEE facilitated the in situ formation of a protective, gradient SEI layer.

Conclusions:

  • The developed HEE effectively suppresses parasitic reactions and dendrite growth in ZMAs.
  • This electrolyte design offers a promising pathway for advanced, high-performance aqueous zinc metal batteries.
  • The eutectic system enables low-temperature operation and enhances electrolyte-anode compatibility.