Aluminum Biorecovery from Wastewaters

Aluminum biorecovery is still at an early stage. However, a significant number of studies showing promising results already exist, although they have revealed problems that need to be solved so aluminum biorecovery can have a wider application and industrial upscaling. In this chapter, we revise the existing knowledge on the biorecovery of aluminum from different sources. We discuss the design, overall performance, advantages, technical problems, limitations, and possible future directions of the different biotechnological methods that have been reported so far. Aluminum biorecovery from different sources has been studied (i.e., solid wastes and primary sources of variable origin, wastewater with low concentrations of dissolved aluminum at pH-neutral or weakly acidic conditions, and acidic mine waters with high concentrations of dissolved aluminum and other metal(loid)s) and has shown that the process efficiency strongly depends on factors such as (1) the physicochemical properties of the source materials, (2) the physiological features of the used (micro)organisms, or (3) the biochemical process used. Bioleaching of aluminum from low-grade bauxite or red mud can much be achieved by a diverse range of organisms (e.g., fungi, bacteria) with different metabolic rates. Biorecovery of aluminum from wastewaters, e.g., domestic wastewater, acidic mine water, has also been accomplished by the use of microalgae, cyanobacteria (for domestic wastewater) or by sulfate-reducing bacteria (acidic mine water). In most of the cases, the drawback of the process is the requirement of controlled conditions which involves a continuous supply of oxygen or maintenance of anoxic conditions which make aluminum biorecovery challenging in terms of process design and economical value. Further studies should focus on studying these processes in comparison or in combination to existing economical processes to assess their feasibility.