PFAS transport under lower water-saturation conditions characterized with instrumented-column systems

The transport of PFOS and PFOA in well-characterized sand was investigated for relatively low water saturations. An instrumented column was used for some experiments to provide real-time in-situ monitoring of water saturation and matric potential. The results showed that water saturations and matric potentials varied minimally during the experiments. Flow rates were monitored continuously and were essentially constant. These results demonstrate that surfactant-induced flow and other nonideal hydraulic processes did not materially impact PFAS transport for the experiment conditions. Air-water interfacial adsorption was demonstrated to provide the great majority of retention for PFOS and PFOA. Retention was significantly greater at the lower water saturations (0.35-0.45) compared to the higher saturations (∼0.66) for both PFAS, due to the larger extant air-water interfacial areas. Retardation factors were 5 and 3-times greater at the lower water saturations for PFOS and PFOA, respectively. Early breakthrough was observed for the PFAS but not for the non-reactive tracers at the lower water saturations, indicating the possibility that air-water interfacial adsorption was rate-limited to some degree. Independently determined retention parameters were used to predict retardation factors for PFOS and PFOA, which were similar to the measured values in all cases. The consistency between the predicted and measured values indicates that PFAS retention was accurately represented. In addition, air-water interfacial adsorption coefficients measured from the transport experiments were consistent with independently measured equilibrium-based values. Based on these results, it appears that the air-water interfacial adsorption processes mediating the magnitude of PFOS and PFOA retention under lower water-saturation conditions are consistent with those for higher water saturations. This provides some confidence that our understanding of PFAS retention obtained from work conducted at higher water saturations is applicable to lower water saturations.