Direct photocatalytic C-H functionalization mediated by a molybdenum dioxo complex
Related Experiment Video
Updated: Jun 23, 2025

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
Published on: September 5, 2018
Courtney L Baumberger1, Victoria Z Valley1, Matthew B Chambers1
1Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803-1804, USA. chambers@lsu.edu.
Abstract:
Direct photocatalytic C-H activation mediated by MoO2Cl2(bpy-Bu), a unique photoactive metal OXO, is presented. The limiting step, reoxidation to the Mo dioxo, is evaluated and proposed to occur via a key Cl- loss event. Photocatalyst degradation occurs upon substitution of bpy-Bu with H2O generated during catalysis.
More Related Videos
10:21Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
Published on: October 5, 2019
06:34Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides CHIPS
Published on: June 20, 2014
Related Concept Videos
Cycloaddition Reactions: MO Requirements for Photochemical Activation
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide
Alkenes via Reductive Coupling of Aldehydes or Ketones: McMurry Reaction
Photochemical Electrocyclic Reactions: Stereochemistry
Selection Rules: Photochemical Activation
Cycloaddition Reactions: MO Requirements for Thermal Activation
Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate