Ozone Loss on Painted Surfaces: Dependence on Relative Humidity, Aging, and Exposure to Reactive SVOCs

Ozone and its oxidation products result in negative health effects when inhaled. Despite painted surfaces being the most abundant surface in indoor spaces, surface loss remains one of the largest uncertainties in the indoor ozone budget. Here, ozone uptake coefficients (γ_O3) on painted surfaces were measured in a flow-through reactor where 79% of the inner surfaces were removable painted glass sheets. Flat white paint initially had a high uptake coefficient (8.3 × 10^-6) at 20% RH which plateaued to 1.1 × 10^-6 as the paint aged in an indoor office over weeks. Increasing the RH from 0 to 75% increased γ_O3 by a factor of 3.0, and exposure to 134 ppb of α-terpineol for 1 h increased γ_O3 by a factor of 1.6 at 20% RH. RH also increases α-terpineol partitioning to paint, further increasing ozone loss, but the type of paint (flat, eggshell, satin, semigloss) had no significant effect. A kinetic multilayer model captures the dependence of γ_O3 on RH and the presence of α-terpineol, indicating the reacto-diffusive depth for O₃ is 1 to 2 μm. Given the similarity of the kinetics on aged surfaces across many paint types and the sustained reactivity during aging, these results suggest a mechanism for catalytic loss.