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Development of PBS/Nano Composite PHB-Based Multilayer Blown Films with Enhanced Properties for Food Packaging
Francesco Palmieri1, Joseph Nii Ayi Tagoe2, Luciano Di Maio1
1Department of Industrial Engineering (DIIN), University of Salerno, Via Giovanni Paolo II, 132, 84084 Fisciano, SA, Italy.
Materials (Basel, Switzerland)
|June 27, 2024
Summary
This study developed advanced biobased plastic films for food packaging using Polyhydroxybutyrate (PHB) enhanced with nanoclays. These biodegradable films exhibit improved mechanical and barrier properties, offering a sustainable alternative to conventional plastics.
Area of Science:
- Materials Science
- Polymer Science
- Sustainable Packaging
Background:
- Conventional plastics pose environmental challenges, driving demand for sustainable alternatives.
- Biobased and biodegradable plastics offer reduced environmental impact and promote sustainability.
- Multilayer blown films are crucial for advanced food packaging applications.
Purpose of the Study:
- To produce multilayer blown films with enhanced functional properties for food packaging.
- To investigate the impact of nanoclays (Cloisite® 30B) and processing conditions on film properties.
- To establish correlations between processing, material composition, and film performance.
Main Methods:
- Co-extrusion of a three-layer film configuration: Polybutylene Succinate (PBS) and Polybutylene Succinate Adipate (PBSA) as external/internal layers.
- Incorporation of Polyhydroxybutyrate (PHB) functional layer with varying Cloisite® 30B nanoclay ratios.
- Manipulation of extruder screw speed and functional layer thickness during processing.
Main Results:
- Optimal polymer/nanofiller dispersion achieved with 5% Cloisite®.
- Improved mechanical strength and barrier properties (reduced oxygen and water vapor permeability) were observed.
- Nanoclay addition led to film stiffening and enhanced barrier performance.
Conclusions:
- The developed biobased films demonstrate enhanced mechanical and barrier properties suitable for food packaging.
- Processing conditions and nanoclay content significantly influence film functionality.
- These materials represent a promising sustainable alternative to conventional food packaging plastics.
Keywords:
PBS/PHBbarrier propertiesbiodegradable polymersblown filmsfood packagingmultilayer filmnanocomposites
