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Updated: Jun 22, 2025

Chemical Precipitation Method for the Synthesis of Nb2O5 Modified Bulk Nickel Catalysts with High Specific Surface Area
Published on: February 19, 2018
Improved Selectivity and Stability in Methane Dry Reforming by Atomic Layer Deposition on Ni-CeO2-ZrO2/Al2O3
Jonathan Lucas1, Nirenjan Shenoy Padmanabha Naveen2, Michael J Janik2
1Department of Chemical Engineering, Louisiana State University, Baton Rouge, Louisiana 70803, United States.
Abstract:
Ni can be used as a catalyst for dry reforming of methane (DRM), replacing more expensive and less abundant noble metal catalysts (Pt, Pd, and Rh) with little sacrifice in activity. Ni catalysts deactivate quickly under realistic DRM conditions. Rare earth oxides such as CeO2, or as CeO2-ZrO2-Al2O3 (CZA), are supports that improve both the activity and stability of Ni DRM systems due to their redox activity. However, redox-active supports can also enhance the undesired reverse water gas shift (RWGS) reaction, reducing the hydrogen selectivity. In this work, Ni on CZA was coated with an ultrathin Al2O3 overlayer using atomic layer deposition (ALD) to study the effects of the overlayer on catalyst activity, stability, and H2/CO ratio. A low-conversion screening method revealed improved DRM activity and lower coking rate upon the addition of the Al2O3 ALD overcoat, and improvements were subsequently confirmed in a high-conversion reactor at long times onstream. The overcoated samples gave an H2/CO ratio of ∼1 at high conversion, much greater than uncoated catalysts, and no evidence of deactivation. Characterization of used (but still active) catalysts using several techniques suggests that active Ni is in formal oxidation state >0, Ni-Ce-Al is most likely present as a mixed oxide at the surface, and a nominal thickness of 0.5 nm for the Al2O3 overcoat is optimal.
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