Atmospheric heterogeneous reactions on soot: A review

Soot particles, composed of elemental carbon and organic compounds, have attracted widespread attention in recent years due to their significant impacts on climate, the environment and human health. Soot has been found to be chemically and physically active in atmospheric aging processes, which leads to alterations in its composition, morphology, hygroscopicity and optical properties and thus changes its environmental and health effects. The heterogeneous reactions on soot also have a significant impact on the transformation of gaseous pollutants into secondary aerosols. Therefore, the interactions between soot and atmospheric substances have been widely investigated to better understand the environmental behaviors of soot. In this review, we systematically summarize the progress and developments in the heterogeneous chemistry on soot over the past 30 years. Atmospheric trace constituents such as NO₂, O₃, SO₂, N₂O₅, HNO₃, H₂SO₄, OH radical, HO₂ radical, peroxyacetyl nitrate etc., are presented in detail from the aspect of their heterogeneous reactions on soot. The possible mechanisms and the effects of environmental conditions on these heterogeneous reactions are also addressed. Further, the impacts of the heterogeneous reactions of soot on the atmospheric environment are discussed, and some aspects of soot-related research which require further investigation are proposed as well.