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Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic
Nadia El Alouani Dahmouni1, Marta Orts-Arroyo2, Adrián Sanchis-Perucho1
1Instituto de Ciencia Molecular (ICMol), Universitat de València, c/José Beltrán 2, 46980 Paterna (València), Spain. isabel.castro@uv.es.
Abstract:
The neutral holmium(III) oxalate octadecahydrate {[Ho2(ox)3(H2O)6]·12H2O} of mixed hexagonal/decagonal (63·103) 3D net topology shows important changes in the magnetocaloric efficiency upon dehydration/rehydration by heating and water vapor exposition to give the holmium(III) oxalate decahydrate {[Ho2(ox)3(H2O)6]·4H2O} of hexagonal (63) 2D net topology through the intermediacy of the elusive amorphous anhydrous compound {Ho2(ox)3}.
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