Marcus Theory and Long-Range Activationless Transport in Molecular Junctions

Sylvain Pitié1, Yannick J Dappe2, François Maurel1

  • 1Université Paris Cité, ITODYS, CNRS UMR 7086, 15 rue Jean-Antoine de Baïf, 75205 Paris Cedex 13, France.

Summary

Electronic transport in molecular junctions (MJs) is polaron-driven and activationless for oligo(bisthienylbenzene) systems. This contrasts with conjugated oligonaphthalenefluoreneimine wires, revealing new insights into long-range charge transport.

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