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Investigating the Effects of Lubricant Infusion Methods on Polymer SLIPS.
Molly Casey1, Florian Dano1, Teresa Busch1
1Department of Chemical Engineering, McGill University, Montreal, Quebec H3A 0C5, Canada.
ACS Applied Materials & Interfaces
|July 2, 2024
Summary
Ultrasonication infusion significantly enhances slippery lubricant-infused porous surfaces (SLIPSs), improving droplet repellency and durability. This method is crucial for optimizing nanoscale textures on various materials for better performance.
Area of Science:
- Materials Science
- Surface Engineering
- Bioinspired Materials
Background:
- Slippery lubricant-infused porous surfaces (SLIPSs) offer unique self-healing and droplet-repelling properties.
- Advancements in SLIPSs focus on surface texturing and lubricant selection.
- Lubricant infusion methods for SLIPSs remain underexplored.
Purpose of the Study:
- To investigate the impact of different external force-based infusion methods on SLIPS performance.
- To compare ultrasonication, vacuum, and hydrostatic pressure infusion techniques.
- To optimize SLIPS fabrication for enhanced wettability, slipperiness, and durability.
Main Methods:
- Fabrication of nanostructured polypropylene surfaces via hot embossing and laser micromachining.
- Infusion of silicone oil using ultrasonication, vacuum, and hydrostatic pressure.
- Analysis of wettability (contact angle hysteresis) and slipperiness (critical tilt angle, sliding velocity).
- Durability testing through repeated droplet impacts.
Main Results:
- Ultrasonication infusion yielded superior SLIPS with a contact angle hysteresis of 13° and a critical tilt angle of 18.3°.
- Sonicated SLIPS exhibited a sliding velocity of 1.66 mm/s, significantly better than drip-infused controls (0.23 mm/s).
- Ultrasonication proved most effective for nanoscale textures on polypropylene and stainless steel, enhancing slipperiness.
Conclusions:
- External forces applied during lubricant infusion, particularly ultrasonication, significantly improve SLIPS performance.
- Ultrasonication is a promising method for fabricating highly effective SLIPS with enhanced durability and slipperiness.
- Further research into force-driven infusion mechanisms is warranted to fully understand SLIPS optimization.

