Environmental remediation approaches by nanoscale zero valent iron (nZVI) based on its reductivity: a review

The fast rise of organic and metallic pollution has brought significant risks to human health and the ecological environment. Consequently, the remediation of wastewater is in extremely urgent demand and has received increasing attention. Nanoscale zero valent iron (nZVI) possesses a high specific surface area and distinctive reactive interfaces, which offer plentiful active sites for the reduction, oxidation, and adsorption of contaminants. Given these abundant functionalities of nZVI, it has undergone significant and extensive studies on environmental remediation, linking to various mechanisms, such as reduction, oxidation, surface complexation, and coprecipitation, which have shown great promise for application in wastewater treatment. Among these functionalities of nZVI, reductivity is particularly important and widely adopted in dehalogenation, and reduction of nitrate, nitro compounds, and metal ions. The following review comprises a short survey of the most recent reports on the applications of nZVI based on its reductivity. It contains five sections, an introduction to the theme, chemical reduction applications, electrolysis-assisted reduction applications, bacterium-assisted reduction applications, and conclusions about the reported research with perspectives for future developments. Review and elaboration of the recent reductivity-dependent applications of nZVI may not only facilitate the development of more effective and sustainable nZVI materials and the protocols for comprehensive utilization of nZVI, but may also promote the exploration of innovative remediation approaches based on its reductivity.