Bismuth oxychloride nanosheets anchored aramid separator with sponge-like structure for improved lithium-ion battery...

Functional modification of inorganic particles is an effective approach to tackle the issue of Li⁺ transport and the lithium dendrites formation in lithium-ion batteries (LIBs). In this study, PMIA/BiOCl composite separators are prepared by nonsolvent induce phase separation (NIPS) method using P-type semiconductor bismuth oxychloride (BiOCl) functionalized poly (m-phenylene isophthalamide) (PMIA) separators. Compared with the polypropylene (PP) separator, PMIA has superior thermal stability and the addition of BiOCl further enhances its flame retardancy. And the prepared PMIA/BiOCl separator presents improved porosity (66.47 %), enhanced electrolyte uptake rate (863 %) and higher ionic conductivity (0.49 mS∙cm^-1). Besides, the incorporation of BiOCl can anchor PF₆^- to the three-dimensional network skeleton of the PMIA/BiOCl separators, enabling the desolvation of Li⁺ and selectively facilitating Li⁺ transport (the Li⁺ transfer number is 0.79). Moreover, the uniform porous structure of the PMIA/BiOCl separators and the efficient transport of Li⁺ uniformly deposite Li⁺, and minimize the growth of lithium dendrites. Batteries assembled with PMIA/BiOCl separators have a discharge specific capacity of 124.4 mAh∙g^-1 and capacity retention of 96.7 % after 200 cycles at 0.2C. Therefore, this work provides an effective route in the design strategy of separators for LIBs.