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Expression and Purification of Nuclease-Free Oxygen Scavenger Protocatechuate 3,4-Dioxygenase
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Singlet oxygen is an emissive ligand

Paul Asselin1, Adrien Schlachter1, Pierre D Harvey1

  • 1Département de Chimie, Université de Sherbrooke, 2500 Boul. de l'Université, Sherbrooke, QC, J1K 2R1, Canada. Pierre.Harvey@USherbrooke.ca.

Chemical Communications (Cambridge, England)
|July 8, 2024
PubMed
Summary

Gaseous singlet oxygen (1O2) demonstrates unprecedented emissive ligand behavior after collisional photosensitization. This finding was confirmed by monitoring its phosphorescence and excited state lifetime under varied atmospheric conditions.

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