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Updated: Jun 21, 2025

Expression and Purification of Nuclease-Free Oxygen Scavenger Protocatechuate 3,4-Dioxygenase
Published on: November 8, 2019
Singlet oxygen is an emissive ligand
Paul Asselin1, Adrien Schlachter1, Pierre D Harvey1
1Département de Chimie, Université de Sherbrooke, 2500 Boul. de l'Université, Sherbrooke, QC, J1K 2R1, Canada. Pierre.Harvey@USherbrooke.ca.
Abstract:
Unprecedented experimental evidence shows that gaseous singlet oxygen (1O2) acts as an emissive ligand following collisional photosensitization. This evidence was obtained by monitoring 1O2 phosphorescence intensity at ≈1275-1280 nm and the excited state lifetime of singlet oxygen generated by known tetraphenylporphyrin photosensitizers, while varying the atmospheric environment.
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