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Related Concept Videos

Induced Electric Dipoles01:28

Induced Electric Dipoles

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A permanent electric dipole orients itself along an external electric field. This rotation can be quantified by defining the potential energy because the external torque does work in rotating it. Then, the potential energy is minimum at the parallel configuration and maximum at the antiparallel configuration. While the former is a stable equilibrium, the latter is an unstable equilibrium.
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
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Updated: Jun 21, 2025

Assessment of Boron Doped Diamond Electrode Quality and Application to In Situ Modification of Local pH by Water Electrolysis
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Photoinduced Charge Injection from Shallow Point Defects in Diamond into Water.

Kang Xu1, Daniela Pagliero1, Gabriel I López-Morales1

  • 1Department of Physics, CUNY-City College of New York, New York, New York 10031, United States.

ACS Applied Materials & Interfaces
|July 8, 2024
PubMed
Summary
This summary is machine-generated.

Diamond surfaces with nitrogen-vacancy (NV) centers generate photocurrents using visible light, overcoming limitations of ultraviolet excitation. This breakthrough enables new applications for diamond-liquid interfaces in chemical and spin processes.

Keywords:
NV centersdiamondphotocurrentshallow trapssolvated carriers

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Area of Science:

  • Materials Science
  • Photochemistry
  • Quantum Optics

Background:

  • Diamond's unique properties, including low electron affinity and chemical inertness, make it promising for generating solvated electrons via optical excitation at solid-liquid interfaces.
  • The wide bandgap of diamond typically necessitates ultraviolet light, limiting practical applications.

Purpose of the Study:

  • To investigate the photocurrent response of single-crystal diamond surfaces engineered with nitrogen-vacancy (NV) centers in contact with water.
  • To explore the potential of visible light excitation for generating photocurrents at diamond-liquid interfaces.

Main Methods:

  • Fabrication of single-crystal diamond surfaces with engineered shallow nitrogen-vacancy (NV) centers.
  • Measurement of photocurrent generation upon optical excitation with visible light wavelengths.
  • Analysis of photocurrent response as a function of laser power.

Main Results:

  • Clear photocurrent generation was observed across the visible spectrum, extending to 594 nm.
  • Nitrogen-vacancy (NV) centers and coexisting surface defects contribute to carrier injection.
  • NV centers were found to dominate the photocurrent response at high illumination intensities.

Conclusions:

  • Engineered diamond surfaces with NV centers enable visible light-induced photocurrent generation, overcoming previous wavelength limitations.
  • These findings pave the way for novel applications of diamond-liquid interfaces in photocarrier-initiated chemical and spin processes.